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The Dufaycolor Process Product booklet

Product booklet for The Dufaycolor Process. 71 pages in English. Read the original PDF, download or print a copy without registration.

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Various brands
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The Dufaycolor Process
Document type
Product booklet
Language
English
Pages
71
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11.9 MB
Category
Photography reference
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Page 2 · Read text
DU   IOR   PROCESS





             PUBLISHED BY
ILFORD LIMITED     ILFORD, LONDON
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                        www.butkus.us
            By courtesy of  Tunbridge.
Rellected light from half.watt    Blocks by John Swain & Son,lamps totalling 2,5oo watts and   Ltd., Screen negatives rnade
two 5oo watt spots. Exposure    direct on to Ilford Rapid Process
3 seconds atFf4.5 on Dufaycolor    Panchrornatic Plates through
Flat Filrn through Dr/z  filter.   Ilford Tricolour Fihers. rio
                                      line screen.
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)DufaycoX.on PnocessThe
             SECTION I
       INTRODUCTNON
       Colour photogruphy is by no means a new invention, but
its use has been gteutly restricted, partly on the ground of expensg
but primarily b""*"  of the necessity for long exPosures and
somewhat difficult manipulation.
      The new Dufaycolor process, which is remarkably easy
to manipulate, will undoubtedly provide a stirnulus to colour
photogriphy which will lead it to ito rightful place in the
photographic world.
      Whenever it is desired to record an event or reproduce a
scene or person in colour, the correct startilg point is a_photo'
      in colour, and now with the Dufaycolol Process this canSaph                                 and with very little moreL i"oduced with ordinary lpparatus*kiil than is required to *o[e a black and white photograph.
From this colour photograph further reproductions can be made
in a variely of ways.
What it  i.s and how it wor[<s
      The Dufaycolor-film  process gives transparencies on a flexiblenon,inflammable       urra repioduces robiects in their full
brilliance of colour. The transparency is viewed by holding it
in front of any convenient difiused light source or by projection
in a suitable apparatus.
      The film consists of a transparent non.inflammabl.e base
on which is printed a very fine transparent colour patte-rn- con'
sisting of allernating blue and green s_quares and red lines.     "patternThis          is callei the "r6seau" and in this the complete
colour pattern (of three colours) is reproduced twenty times
                                                               fineness,per millimetre or 5oo times per inch. Its extreme
*-ill, therefore, be readily appreciated.
      The method of preparation of the reseau is a natter of
much interest and also of lte"y considerable practical difrculty;
                                3
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      The DUFAYCOLOR Process

the main stelx in the process are shown in the illustration on the
colour plate opposite, and the following is a brief outline of the
procedure:-
      The base is first coated with a very thinlayer ofcollodion
dyed blue; afterwards a set of greasy ink lines is printed at an
uoglu to the length of the roll, there being twenty lines to the
millimetre and the spaces between being equal in width to the
lines. The method of printing is comparable with that of
letterpress printing and it will be appreciated that the machinery
required to produce such a result is a triu-ph of engineering
enterprise and skill.                                                                                                                                                                                                                      I,l
       In the next operation the dye between the ink lines is                     .l
bleached and the second dye bath results in the clear spaces                       I
being coloured green. The ink lines are now removed and a        cta
second set printed at right angles to the first. The lines this
time are broader than in the first instance and the spaces between
are narrower so that there are the same number of lines per
millimetre as before.
      The second bleaching bath now removes the green and
blue dyes where there is no protective cover of ink. In the final
bath these clear spaces are dyed red, and lastly the ink lines are
removed. The reason for making the red lines narrower is to
approximately equalise the areas of red, blue and green.
     On top of the r6seau to protect it, there is a very thin
layer of varnish and then a coating of a special very hlghly
sensitive panchromatic emulsion (see Fig. r).

        .ADHESIVE TAPE             EXPOSE ]TIIS SIDE                          NON FLAI.I SASE

                                                                                            t
                                                                        RESEAU           I                   Y

                                                                     THIN VPRNIsH I.AYEA




                                                                                        PROTECIIVE
                                                                                  PAPER. COVER
       FIG.I. CROSS SECT|ON THROUGH PIECE OF DUFAYCOLOR FILM

      The film is exposed through the base so that the light
passes through the colour r6seau before reaching the emulsion.
                           4
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PHOTOMICROGRAPHS OF DUFAYCOLOR RESEAU.
                                    Magnification Xroo Linear.





               (t   Base dyed blue, then              (")  BIue bleached
             over,printed with  greasy
                       resist in lines.
*4

    {'





                      (:)  Dyed grecn.             (+) First resist washed off
                                     and reprinted in lines at
                                                  right angles to the first set.





                                                (6)  Dyed red and resist re-
                                        moved to give final reseau.
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                                            Process         The DUFAYCOLOR

     In this way the image is broken up into three sets of minute
      areas which represent respectively the red, green and blue
     components of the subject photographed.
             Consider now a red object photographed on Dufaycolor
     Film; the red light passes through the red areas of the
     r6seau but is stopped by the green and blue areas. On
     development there rvill be a black silver deposit behind each red

                                          BLUE'      GREEN       RED
                       ''ln'        LIGHT        LIGHTI           LIGHTI                                                               Y               Y                                    {


                ilmR,-FrR,sT
              DEVEIOMAENT





             AFTB.
             IIEACHINO





             ATT€R
                 Rl-DEytlort|a|l

                              I               I              I               I
                         WHITE          BLUE        GREEN
                                                         FIG.2. REPRODUCTION                             gtVER Bf,OMIDE EMUISION                                                OF COLOURS BY
                                 DEYEI.OPED ATVER IMAGE            DUFAYCOLOR
                        GELANN AFTERDigitallyDN: cn=MikeREMOVALsignedButkus,by Mikeo=ButkusOFButkusSIIVERcamera manuals,IMAGEou=butkus.org,
                                                             email=mike@butkus.org, c=USMike Butkus                    Date: 2023.03.21 20:13:24 -04'00'
       filter element, the silver bromide behind the blue and green
     elements being unafiected. The next step in the processing of
     the film is the bleaching operation, which dissolves away the
     developed silver without affecting the unexposed areas. An even
     exposure to white light is then grven to make these unexposed
     areas responsive to a final treatment with developer, which
     converts all the remaining silver bromide to silver. Thus
       it  will be seen that there is now a black silver deposit

                                           5
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Process       The DUFAYCOX,OR
 behind both the blue and green areas. When the film
                                                             red is illuminated the light     only Pass through .h1                          "uo-                              accurate rePresentation of the  filter elements and thus an
  original red object is obtained. Similar reaJoning ?PPltT to the
               of any_other_ colour and the three colour elements
  ""p"rodo"tion           are such-that all colours can be reproduced. See Fig. z. eriployed
'       The fineness of the r6seau pattern avoids any coarseness or
  graininess in the image when viewed in the hand or when pro'
  j"ected on the screen,          the magnification is not excessive'                    frovided
                                                                 eye_ by         since the final colour picture is formed in the
  adding together the light transmitted by all the seParate colour
                  i'f th" r6seau] this process is known as additive colour  "I"*"it  photography.
       the principles of this for* of            were first                                       -photoflophy  laid down in 1869, while the first colour ltlates were lrld'rrll'
  factured in 1895, and throughout this period uplo the present
 day many i*iiov"orents hive been made. Dufaycolor i1 the
  lut"rt of ihit fong line of processes and is the outcome of con'
  tinued and concJntrated ,lsearch, which has been carried on
 with the sole purpose of obtaining accurate colour rendering
  combined with-uo     method of manipulation.                    "uty         Dufaycolor takes its name from M. Louis- Dufay, who
  manufactot"d the Dufay Diopticolor and Dioptichrome Screen
  Plates in r9o8 and has ,irr"u b"9" e,ngaged_ in tlie- developing of a
  colour mafrix on film sufrciently fine io be applicable to colour
  cinematography. such a prgcgss could ogt reach perfection
  without iL"             df lutgu sums of money and much               "*p""diture                         research, both of which have been made  co,op€rative scieltific
   ulruiiuble by the foresight of Spicers Ltd.-arrd Ilford Limited,
  who have c-o,operated  ii the development of this Process and have
  brought it to its present_stage of perfection. Intensive experimental
  *o"f  is proceed^iog uod        improvements are being m'ade'                          "Jortait
 The Advantages of D'affaYcotror
          Dufaycolor is the most perfect syste_m of additive.colour
  photography yet devised in tlat  it combines the following
  improvements  over all previous Processes:
                            6
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      The DUFAYCOLOR Process

        (r) Considerable increase in speed, permitting snaphot
 elposures with ordinary inexpensive cameras under a wide range
 of conditions.
       (z) Greater latitude in elposure
                                                              screen         ft) Finer and very much less obtrusive colour
elements.
       (4) Absence of frilling and blistering.
     G) Absence of parallax.
       (6) Ease with which three,colonr separation negatives
can be made for preparing colour photographs on paper or
colour blocks for machine printing by any process.
       (7) Ability to make duplicate transparencies without
serious loss of colour.
Tlpes of Dufaycolon lFilm
      There are two types of Dufaycolor Film:
    Tyae D.r   . .                Film Packs and Films for Leica and                  *r,Ttl"T*l,.
    Type D.a      for Flat Film and sub,standard Cinematogrephy.
  Note:-Yariations of this method of packing cannot be undertaken, tfius
Typ" D.z material will Not be packed as Roll Film, etc.
       Typ" D.r Dufaycolor Film is suitable for exposure in day,
light without any                  fiher and is therefore particularly suitable for
the amateur user. A filter is necessary for ltgha other than
daylight.
      Typ" D.z Dufaycolor Film requires a fiIter under allci,rcumstances (see page ro). It has been decided to market this
type of material for Dufaycolor Flat Film because the highest
possible speed and colour correction is obtainable in this way,
with the various light sources which may be used in practice.
Flat Film therefore grves the perfection required for technical
work. The necessity. for using a filter does not lead to Typ"
D.z material with filter being slower than the Typ" D.r
without filter in daylight.
     A further difference is that the Flat Film is on a thicker
non,inflamnable base to make it suitable for use in large sizes.
                             7
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SECTION II

    \MORKNNG NNSTRN.JCTIOI{S
     The development technique and subse_quent tre_atment
recommended in the following sections of this booklet are
applicable to both the Type D.r and Typ" D.z materials.
       Arrangemenrs have been made by Ilford Limited for the
processing of Roll Films and sub,standard cin6 Films, so that
                                                            materials.|rocessin[ instructions are not issued with these
FUt a"tuits are, however, gven in each carton for loading the
camera, etc. In the case of nilm Packs and Flat Films full
processing instructions are enclosed in each box but the
iollowing pages give further information which will  enable
even the-novice to carry through the neoessary operations.
Flat Film-Loading the Dar[< Slide
      Owing to the extreme speed and colour sensitiveness of
the emulsion on Dufaycolor Film, it is essential to carry out all
loading operations in complete darhness. A little experience yill
soon        this to be done. If the bench is clear and the worker     "iu6l"stands          still there is little difficulty in doing everything by touch.
The film is packed six sheets in a box, all facing the same direction,
and each piu." of film has hinged to it at one end a sheet of black
paper of exactly the same size which covers and. protects the
                                                        beioi.rlrioo.coated side (see Fig. r). This PaPr should notremoved until immediately before development, when it should
be opened our and a gentle sideways pull will cause the
adhes^ive strip to peel eveoly off the film without tearing (see
Fig. :).
      As previously mentioned, Dufaycolor Film has to be
'uxposed through the base and therefore special care must be
tut"o in loadingi the base side can be recognised readily j" .1"
 dark because it is smooth to the touch and is not protected by the
paper cover. Care should be taken, however, not to impress
                             8
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                                       Process      The DUFAYCOLOR

finger prints on the base, since thel' -1y _b-e recorded on the
        during exposure. Where film holders or sheaths are"-itl.idoavailable, these may be used successfully, but it is importa:rt
to insert first that end of the film which is attached to the
backing paper so that the emulsion is adequately protected from
scratches and the paper cannot crease.





                                Fig. 3.
       For use in plate dark slides of the single metal type, _the
                                                         afiln may be placed with its paper protector in contact with
sheet of thin fiat glass and then the edges joined to th9 glass with
narrow strilx of ihin adhesive tape. If it is preferred to use stiff
                                                                                                                                                          4cardboard in place of glass it is desirable to use best quality
cardboard, otlierwise t[.e emulsion may be fogged if stored for
long in this way.
      With some double dark slides it may be better to Put the
film behind a sheet of glass, that is to say, the glass is_inserted
 first, then the film with its emulsion side away from the glass.
This prevents any difficulty due to curlin_g of the film, but neces,
sitatei allowance being made for the thickness of the glass when
 focussing, unless the exposure is to be made at a very small
aperture. The thickness of the glass can be comPensated for
 ajutomatically by reversing the ground glass of the focussing
screen so that the plain side of the glass is towards the lens.

                                                                                                                                                          /Fitrters        Since different light sources vary very greatly in their
                                                             use spectral composition it is necessary in colour work to
 J difi"r"ot filter for each type of light, and in order to obtain
 the best results on Dufay"olor Flat Film under all conditions,
 special highly efficient fiIters have been m,ade for use with
 each type of light. (See also page T.)
                            9
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The DUF'AYCOLOR Process

      The following are the filters which are available for
 Dufaycolor Type D.z.
     Code Number.
        Dr/t         for Daylight.
       Dt/z        for Half,watt Light (including high eficiency or Pro,
                         jector type lamps) and Pointolite.
      D"/S        for Photoflood and similar types of lamp.
      D"/+       for Sashalite and similar types of bulbs.
      Dr/S    . .   for Arc Light (white,flame carbons).
         Filters can also be supplied for other special purposes on
request, but full details must be given when ordering.
           It will be noticed that flashlight is not mentioned above,
because different makes of flash powders differ greatly in the
colour of the emitted light.  Flash bulbs of the Sashalite type
are preferable and more reliable.
       For Dufaycolor (Typu D.t) Roll Films and Film Packs
                                                                are(see page 7), filters issued under the D.r code number
required as follows:-
     Code Number.
      No filter. .   for Daylight.
      Dr/z        for Half,watt Light (including high efficiency or Pro,
                  i::Tilli-i"Hm):*ff:ill1r;f  ramps.   D./t      Dt/+        for Sashalite and similar typ& of bulbs.
     IMpORTANT NOTE. In order to prevent errors ir is
desirable always to refer to filters by their code numbers.
Filters made for orthochromatic or panchromatic materials are
of no value for Dufaycolor.
        Filters consisting of gelatine film are ideal for experi,
mental work, as they are cheap and reliable wheu properly
handled. It is essential that they should not be buckled or
have finger marks, as they may then produce double images and
other defects. They should be handled only by the edges and
stored between paper and they should not be stuck 1o any
zupport. The most satisfactory way of employing a gelatine
filter is to place it between the lens components.
   -   For regular use cemented glass filters should be employed.O"ly the B quality filters are recommended, as the cheaper A
qualiqy are not suitable for high,class colour work.
                             l0
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      The DUFAVCCLOR Process

        Glass filters preferably should be placed in front of the                                              ^but Iens, as they will nofthen affect the focus,        if placed berween
 the lens and the film it will be necessary to focus on the ground
 glass as the focussing scale will be inaccurate. Dufaycolor Filters
 can be supplied in three different types of filter mounts.
          It should be pointed out that a Dufaycolor transparency
 will look correct in colour only if viewed in daylight, no matter
what light was used for exposing, provided the correct taking
 filter was employed. If it is desired to view in any other light, a
 suitable compensating viewing filter should be used. (So
Page 33).
Focussioug
        Focussing is very important since transparencies which
 are not quite sharp are usually very ineffective. As mentioned
 previously the emulsion is on the back of the film during expos,
ure. With the ordinary type of camera with a lens aperture
                        have no effect, but when lenses of veryf /+.5 or smaller this will
large aperture and short focal length are employed special care
 will be needed to ensure correct focussing. It is also very import,
ant that the film should be held flat and in the correct plane. If
results are obtained which are not sharp the method of holding
the film should be examined.
Exposure
     To obtain first,class colour transparencies, considerable
accuracy in exposure is essential, even though Dufaycolor Film
has greater latitude in this respect than any other colour,screen
process. Variations in exposure of at least 8 to r will not cause
serious divergencies in the colour positives if they are processed
individually in accordance with the methods given here. If all
exposures are developed for a fixed time, the latitude is of the
order of .4 to r, but can be increased by subsequent reduction
or intensification. Nevertheless, transparencies of maximum.
brilliance will only be obtained by correct exposure.
       Hence, we wish to stress the importance of accurately
estimating all exposures. Success in this direction may depend
very largely on personal skill and experience, but the fol,
lowing notes will enable this experience to be gained very

                                    11
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Process       The DUF'AYCOLOR

  rapidly. The table given below will be found to be a reliable
  guide for all outdoor exposures on Dufaycolor, but it will be
  noticed that special categories are not given for different types
  of subjects since in colour photography the correct exposure re,
  mains the same whether the subject is relatively near to or far
  from the camera and whether or not the subject includes
  shadows; this is because exposure should be correct for the high,
  lights. Hence, subjects including both very dense shadows and
  strong high,lights should be avoided as far as possible. The
  times grven below are for the film in conjunction urith its day,
  light filter in the case of the Type D.z material, or without
   filter in the case of Roll Films, etc., Type D.r.
                  f+   fs.c  fs   fn    f'6  Beach and sky soenes   r/zoo   tftoo   r/5o    t/rs     rfto
  All outdoor subjects in  rfroo   t/so   t/>S    tfrc     t/S
  sunlight except the above
  AII outdoor subjects on t/so    t/r5     lrc     t/S      t/"  bright days with  sun
  obscured
  AII outdoor subjects ;;
  dull days                         lrc      t/S       t/*        r                            '/rS
  These exposures are correct for the middle hours of the day
  during the summer months. For other times and seasons multiply
 by the following factors:-

                          April, May,                           November,
     Time of day       June, July,     March,                 December,
    (not summer time).     August.      September.                 January.

    a.m.   P.m.      roto2                         I             ,            ,             I
     8-ro or r,-^4                   I             ,              I
     6-8 or ,4-6          ,                I
I As further useful evidence of the speed of Dufaycolor to daylight
I it *uy be             said that it requires Lpproximately lwice the ex'
I ooror" of Selo Roll Film or four timis that for Selochrome Roll
L i it*, when the exposure^Again,for the latter materials yields well
f explsed negatives.         Dufaycolor is slightly _slower than   tt   Ilford Special Rapid Panchromatic Plate to daylight andI   "
                                 l2
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                                        Process      The DUFAYCOLOR

only upproximately one,third the speed of the latter to half,
watt light when it is used with its appropriate filter and the
plate without a filter.
        Naturally, the use of a reliable etlPosure meter will give
greater accuracy than is possible with either of the above
methods. Photo,electric exposure meters are particularly
applicable to colour photography because thel record primarily
t[e light from the brighter parts of the subject. Hence the
reading grven by the instrument is usually correct without
multiplying by any factor intended to compensate for nearness
                                CELL WINOOW

                                RED SCAL€
                                     BLACK SCALE

                                  GREEN SCALE      NEEDTE
                                       BLACK ARROW
   r/nur,reens
                                                       RE D ARROW

 GREEN ARROTT/
                                               IXED
                                       CENTRE EOSS

  MILLED
OUTER DISC

of subject, depth of shadow, etc. The Ilford Photo'Electric
                                  and yet most- reliableExposure Meter (FiS. 4) it of the simplest
     and can be strongty recommended for use with_Dufaycolor;
"yp"experience shows that w"ith an exposure,-"t9t of this type the
 peicentage of perfect exposures is very high. This- exPosure P"F" is not ooly rrrituble for outdoor work but is a reliable gui{e for
indoor subjects taken by daylight when the exposures _do_qot
 exceed one second; also if the mete" readings are multiplied by
        be found to be a useful g"id" to studio exposures with5 it will
                                13
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rI
                                                                                                                                                                 t
                                                                                                                                                                                                         r
                                                                                                                                                                                                                                                                            f

                                                                                                                                                      1      The DUFAYCOLOR Process

                                                                                                                                                                IT                 lanps. When Photoflood Iamps are em,                      r $lflrlat_t (gasfilled) ployed_ the factor by which the meter readings uhoua be
                                                                                                              F                               details for the use of th" Ilford multiplied is also 5. Full
 Photo,Electric Meter are supplied with the instrument.
       For further notes on Photoflood lighting see p. 27.
Points to Renaem.ber    '       In colour photography it is well to remember the fol,
 lowing points:-
                It is not necessa,ry when using Dufaycolm rnaterial
        to         _seeh for lytghtly coloured obiects tb ph,otograph. Dufay,
      colorshould be employed in the normal wuy,pho?ogruphing
     the ordinary colours met with in Natur", wheo ihd-ori
      pleasing efects will be obtained.
         The best transparencies are usually those taken
     ytth the lens at a wide aperture; therefore, do not stop                                                     I
    down much, unless it is esJential to do so to obtain deptl     of focus.                                                            I
  -            Strong contrast in the lighting is not required, as
     the colour provides the contrast.
              Brilliant sunshine grves brilliant colours and is,
      therefore, desirable, but heavy shadows may result which
      are not always pleasing.
          Large masses of colour are more efiective than
     small scattered patches.
            Colour pictures should, if possible, be taken with
     the light_behind the camera: photographing against the
      light is often disappointing.
          Under exposure leads to dense results and hard
     contrasts, while over exposure grro  light  colours
    and lower contrasts, unlesJ the       in exposure are
     subsequently_                   by the development"rtors       technique                   _corrected
    recommended here.
Processing
         It is important to follow closely the instructions given_here, since ooly^ in this way will the 6est results be obtalned.
Dufaycolor Film possesses the valuable property of withstanding
                              t4





                                                                                                                                     h
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           The DUFAYCOTOR Process

          continual treatment in a variety of baths under all normal con,
           ditions without frilling, blistering, or other defects; rherefore,  it
          will be found quite easy to carry out the processing operations.
        The so,called reversal method of processing must be ernployed to                                                             -piece         produce_ a colour transparency (positivQ from the        of
         Dufaycolor Film which is actually exposed in the cum&a. On                                               -obtained          developing, a negative image is first           but, instead of
          fixing at_ this stage, the black silver negative image is dissolved
          out in a bleaching bath, the remaining silver bromide is exposed
           to light during the second exposure and then redeveloped to give
         the final positive. This procedure presents no diffi"ul?y in piac,
           tice and can be carried out by any amateur.
             The use of most ordinary developers on Dufaycolor Film
          willlead to failure, and itistherefore desiiable to usethedeveloper
         formula recommended and to follow the instructions closely.
              For the convenience of different rypes of workers, two
          elternative development techniques are given. Where the work
             is mainly repetitive or the conditions of lighting are srandar&sed,
         the exposures should be accurate and a standard developmentt         time will give the best result. Should errors in exposure occur
         the resulting transparencies will be too thin or too dense and
       can be partially corrected by reduction or intensification, as
         explained on page 2,r.
              For the amateur or other outdoor worker who cannot
         control his exposures so accurately, a method of Factorial
        Development is of great vaJue, since small errors in exposure are
          autornatically compensated for and larger errors are made to
          yield the best results obtainable under the circumstances without
        the necessity for any after treatment. But if Constant First
        Development is preferred, the after,treatment can be made to
         yield as high a percenrage of good resuks as would be obtained
        by Factorial Development.
t             whichever method is ernployed great care must be taken
 I       to avoid fogging, as the speed of the emulsion is exceptionally
       high.           fogging, as from an unsafe darkroom ^lu*p, is               -Unifnrm         not readily detected, as it does not lead to veiling in rhe ordiiary
         sense, but causes a general flattening of gradaiion and colour,
         together with a loss oU U"^trt;,
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\


                                       Process      The DUFAYCOn-OR
     CONSTANT FIRST DEVELOPMENT METHOD.                                      ((G"Work in total darkness or with an Ilford      Safelight shielded
so that the direct light cannot fall on the film.
      Immerse in one of the following developers for three
minutes at 65oF. (two,and,a,half minutes at TooF: or two
minutes    7fn.), vigorously rocking the dish the wholetime;         "tincreases thJbrilliance of the transparencies. Formula Bagitation
gi.r". slightly more contrasty results than A and has the advan'
i"ge thui the thiocyanate is a more constant and stable chemical
than ammonia. When using the formula A it is important to
ensure that the ammonia is up to its labelled strength.
DE\IELOPER A
     Metol                         r3o grs.               6'5 g-t.
    Sodium Sulphite (cryst.)                I ozs.          roo   ,,
     Hydroquinone                   40 grs.               2'o     t,
                                                   ,.75  ,,     Potassium Bromide            50  ,,
    Ammonia (Sp. G. 88o)           zro minimc             rr  c.ct.
    Water uP to                    1o ozs.          rooo    ,,
DEVELOPER B
     Metol                       ..r30   grs.            6.5 gms.
                                                      OZS.            roo    ,)     Sodium Sulphite (cryst.).  .           I
     Hydroquinone                   1o   grs.           2'O    ,,
                                                roo    ,,     Sodium Carbonate (cryst.)            I                                                     ozE.        or(     Potassium Bromide             50  grl.            2'75  ,,
     Potassium Thiocyanate (sulphocyanide)
          (p*")                                    .  . 16o   gru.               9',                                                                o7,8.           rooo c.cs.       Vy''ater up to                  1o
                                                           theIt is important that the chemicals should be dissolved in
order gr*o.  Alternative am.monia strengths are Ammonia
Sp. G.-9ro:z9o minilns or 15 c.cs.; Solution of Arnnonia
                                        c.cs.B.P.: r oz. r7o minims or 3.4
       These developers do not keep indefinitelyi  if a stock solu,
tion is to be kept, tlh"o formula B is preferable, but it is not
 advisable to use this if more than two or three weeks old. If
old developer is employed rather weak and flat transparencies
will be obtained.
          It is preferable to use fresh developer for each film
 unless several^films are developed at the same time; the used
 developer malt however, be imployed again for the second
 development process (see page zo).
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      The DUF'AYCCtOR Process

            I When it is desired to develop u number of films together
 it is essential that thgl should be held on some ngd supporr so
 that they do not        one anorher and to ensureihut thi edges                   -overlap do not curl out of the solution. A sheet of Ilford Filmflat mounled
 o_n gfass can be used, the film being squeegeed into contact with
 this before commencing development, when it will adhere firmly.
Yh"l  pr_ocessing_is _completed the film is srripped off and the Filmflat thoroughly dried, when it is ready for re,use.
      FACTORIAL FIRST DEVELOPMENT METHOD. FoT
 Factorial Development to be employed, it is essential to desensit,
 ise the errulsion in order that the progress of development can be
watched. While there are a number of desensitisers available,
.lZ  are not necessarily all suitable for use with the special
developers containing silver solvents employed for the reietsal
development of colour films.
       For Desensitising immerse the film in total darkness in a
 r  : 2ooo solution of Pinacryptol Yellow for two minutes and
then rinse for one minute and truttsfer to the developer.
        After desensitising, the Ilford Iso Safelight (red) should
be employed, and, rsing_this safelighr in a darliroom lamp con,
       a z5.w_att bulb, the film should not be exposed to its lightlainjng
for long periods, nor at a shorter distance than tlree feet.
     The Development Technique recommended is as fol,
lows:-Take two dishes and in the hrst pur one part of either of
the de'eloprs given above and three puti. of waier, and into the
second dish pour full strenEh developer. After the two minutes
desensitising and oneminute rinsing, tiansfer the film to the weak
developer and note the time required in seconds for the first
appearance of the image. The brightest high.lights, such as
sky, etc., can be ignored. Immediate-ly this tiire h-as been noted
transfer the film to the full strength developer and continue
dcvelopment without further inspection for i period equal to
three tines the period in the fiist bath. the ?ish should be
rocked continuously throughout the whole period of develop,
ment.
          Itis not satisfactory to give less than two minutes or more
than five minutes in the full Jtrengthdeveloper at65"F., asthis
would indicate that the film is so fai ov€r, or irnder,exposed as to
                                17
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Process      The DUFAYCOLCR

be beyond correction by this method; at higher temperafirres
development for rather less than two minutes may be required for
a fully exposed film.
      BLEACHING BATH. After development rinse thefilmfor
^abouttwo minutes or place immediately in a one per cent solution'of   acetic acid to stop divelopment. Then transfer^to the followilg
bath for five minutes until all the negative silver image is dissolved.


                                                                                                                                                                                                                                                                  .|                                          2 gms.      Potassium Pennanganate.  .        *o 9".''.
      Sulphuric Acid (conc.)                . .2oo mlnms    ot    IO  C.CS.                                                               I
                                                                                                                                                                       I       rooo c.cll.     Water up to                      .. 1o ozs,
          It is important to agitate the film during the bleaching
 operation.
         In making up this solution it should be remembered that
 the perrnanganate may take some hours to dissolve completely
 and the sulphuric acid should be added a few drgps at a time
 and not suddenly. It is desirable to use water free from any
 appreciable quantity of chlorides or else a trace of free silver
 nilrate (ro grains or o'j gm.) should be added, as this will
 prevent ih" det""ioration of the solution during storage. The
 solution should not be kept after use.
       White light may be turned on in the darkroom when the
 filn has been in the bleaching bath for about one minute, and
 all subsequent operations carried out in the white light.
      CLEARING BATH. After bleaching, the film  is
 rinsed and placed in the following bath      the brown stain                                                      'rntil
 has disappeared:-

                                                                      gms.       Potassiurn Metabisulphite                      I  OZ.       I     r   25                                                          torl     Water up to                          .. 1O ozs.     J      ( rooo c.cll.
      ALTERNATI\IE BLEACHING BATH. Some workers
 prefer the bichromate bleach because it is more stable and no
 clearing bath is required after it, thus obviating one o_Peration.
  If the Fi"hro*ute Fleach is used the resulting Dufaycolor trans,
 parencies will be definitely softer and more de_graded in colour.
 Fo" some purposes these relatively degraded efiects may be
 considered more pleasing and harmonious.
                                 18
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      The DUF'AYCOtOR  Process

       Bleaching requires three to five ninutes in a bath prepared
by diluting r part ofthe following solution with r o parts of water.
     Potassium Bichromate     2 o7,s.                                                    I          r   50 gms.                                                    roo c.cs.     Sulphuric Acid conc.           I  ,,    I  o"   .{   Waterupto..             .. qo ,,  J       L rooo ,,
        Dissolve the bichromate in the water fust and then add
the sulphuric acid.
     REDUCTION OF DENSE TRAI{SPARENCIES. When
the film is viewed in white light after bleaching  it will be
obvious whether or not the exposure has been satisfactory. A
correctly exposed film will show the brightest portions of the
highJights as almost dead black when the film lies face up in the
dish: this is because the image in these portions should be
almost free from silver bromide. If on the other hand the high,
lights are covered with a white veil it follows that the exposure
has been too short, or if  Factorial Development has been
employed the correction has either been insuffi.cient or the
exposure so short that adequate compensation is impossible. On
redevelopment this white veil will yield a silver deposit, so that
the transparency will either be flat or unduly dense. This can
be avoided and the transparency consequently improved by
carefully regulated reduction before the second development,
but if the reduction has to be carried far the picture will tend to
be unduly soft in contrast. This treatment is of great value in
practice and was employed as long ago as rgog when it was
included in the instructions for the Thames Colour Plate but
more recently it has been less employed than its obvious merits
would warrant.
     The best reducing agent is a very dilute solution
(r : rooo) of potassium cyanide; a stronger solution acts too
rapidly. This substance is extremely poisonous and must
therefore be handled with care; those who prefer not to use
cyanide can employ   r per cent solution of hypo or a 2 per               ^cent solution of ammonium thiocyanate (sulphocyanide), but
these give less satisfactory results. The film is immersed in the
reducing solution and gently rocked until the high,lights are
almost clear, but are still just covered with a slight milky
deposit; the action is stopp"d by transferring to water. After
                              19
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